This BITSAT free papers is designed to help you prepare for the BITSAT Chemistry section.
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A mixture of carbonates of two bivalent metals contains 13.6% of one metal. If 2.5 g of the mixture liberates 1.33 g , the % by weight of the other metal is
12
13.44
113.6
15
A pyrolusite sample containing 80% will oxidise the same amount of oxalic acid as 37.12 ml of parmagnate solution , of which 1.0 ml will liberate 0.0175 g of from . The mass of the
2.78 g
1.278
0.278 g
27.8 g
0.816
0.136
0.0227
0.272
40 ml of 0.05 M solution of sodium sesquicarbonate is titrated against 0.05 M . x ml of is used when phenolphthalein is the indicator and y ml of is used when methyl orange is the indicator in two separate titration. Hence (y-x) is
30 ml
80 ml
180 ml
120 ml
1
4
2
8
5
3
0.36 g of Iron Pyrites is heated strongly in air. The thus produced is passed through acidified solution. The moles of acidified solution used in redox titration
None of these
20
10
30
In an experiment, 50 ml of 0.1 M solution of a metallic salt reacted exactly with 25 ml of 0.5 M solution of sodium sulphite. In the reaction oxidised to , if the original oxidation number of metal in the salt was 3, what would be the new oxidation number of the metal
0
24.8 g
49.6 g
0.248 g
12.4 g
An aqueous solution containing 0.10 g (Formula wt. = 214) and an excess of KI was acidified with HCl. The liberated consumed 45.0 ml of thiosulphate the molarity of sodium thiosulphate.
22.4 litres of and 22.4 litres of both at S.T.P. are mixed together. The amount of sulphur precipitated as a result of chemical calculation is
23 g
48 g
96 g
16 g
One litre of is passed over hot coke. The volume becomes 1.4 litre. The percentage composition of product is
None
0.8 litre
0.6 litre
0.6 litre and 0.8 litre
In the gaseous reaction of the type which is wrong
a g of A combines with b g of B to give C
a mole of A combines with b moles of B to give C and
a molecuels of A combines with b molecules of B to vive C and D
a litre of A combines with b litre of B to give C and D
Rutherford’s scattering formula fails for very small scattering angles because
The impact parameter between the -particle source and the nucleus of the target is very large compared to the size of the nucleus
The gold foil is very thin
The kinetic energy of the particle is large
The full nuclear charge of the target atom is completely screened by its electron
For an electron in a hydrogen atom, the wave function, is proportional to , where is the Bohr’s radius. What is the ratio of the probability of finding the electron at the nucleus to the probability of finding it at
Suppose J of energy is needed by the interior of human eye to see an object. How many photons of green light () are needed to generate this minimum amount of energy
28
39
42
14
Which of the following parameters are the same for all hydrogen –like atoms and ions in their ground states
speed of the electron
radius of the orbit
energy of the atom
orbital angular momentum of the electron
Difference between nth and (n+1)th Bohr’s radius of ‘H’ atom is equal to it’s (n-1)th Bohr’s radius. The value of n is
Three photons coming from excited atomic hydrogen sample are picked up. Their energies are ‘2.1 eV, 10.2 eV and 1.9 eV. These photons must come from
a single atom
three atoms
two atoms
either two atoms or three atoms
Spin of electron is
rotation of electron about it’s own axis
clockwise and anticlockwise rotation of electron
an intrinsic characteristic of electron connected with its magnetic field
a quantum number which depend upon direction and speed of rotation of electron
The wavelength associated with a golf ball weighting 200 g and moving with a speed of 5 m/h is of the order of
The quantum numbers +1/2 and –1/2 for the electron spin represent
Rotation of the electron in clockwise and anticlockwise direction respectively
Rotation of the electron in anticlockwise and clockwise direction respectively
Magnetic moment of the electron pointing up and down respectively
Two quantum mechanical spin states, which have no classifical analogue
Which of the following statements are correct A – All substances have magnetic properties B – There are substances in which all electrons spins are paired C – There are substances in which one or more electrons have un paired spins D – The greater the number of unpaired electrons, the greater the paramagnetism per mole of substance
CD
ABCD
AB
DA
A radioactive isotope x with half life of years decays to y which is stable. A sample of rock from the moon was found to contain both the elements x and y in the ratio 1:7. What is the age of the rock
A radioactive mixture containing a short-lived species A and a long-lived species B. Both emitting -particles at a given instant emits at rest, 10,000 -particles per minute. 10 minutes later it emits at the rate of 7000 particles per minute. If the half lives of the species are 10 min and 100 hrs respectively then the ratio of activities of A:B in the initial mixture was
6:4
None of above
4:6
3 : 7
The probability of survival of a radioactive nucleus for one mean life is
In
Half life of a radioactive substance A is 2 times the half life of another radioactive substance B. Initially the number of nuclei of A and B are and respectively. After three half lives of A, number of nuclei of both becomes equal, the ratio is
At radioactive equilibrium, the ratio between the atoms of two radioactive elements A and B was found to be : 1 respectively. If of the element A is years, then of the element B is
25.2 MeV
16.6 MeV
20.8 MeV
23.6 MeV
neutron emission
positron emission
Which among the following is wrong about isodiaphers?
Nucleide and its decay product after -emission are isodiaphers
They have the same difference of neutrons and protons or same isotopic number
All correct
Among the following nucledes, the highest binding energy per nucleon is found for
The number of peroxide linkages in are
Two
One
Three
The molecule which has T-shaped structure is
In solid phase, exists as
Which of the following halogen has highest bond dissociation energy
F-F
Br –Br
Cl – Cl
I – I
Structure of is
tetrahedra
distorted tetrahedral
square planar
triangular planar
The correct order of increasing bond length of , and is
ABC
BDC
ABD
In which excited state iodine shows hybridisation state
third
zero
second
fist
Formation of which of the following anion is not possible
There are four molecules , and . Which of the following is correct about these molecules
all are linear but only , and have sp hybridization on their central atom
all are linear and having sp hybridization of central atoms
all are linear but only and have sp hybridization on their central atom
If one assumes linear structure instead of bent structure for water, then which one of the following properties cannot be explained?
the high boiling point of water
solubility of polar compounds in water
ability of water to form co-ordinate covalent bond
the formation of intermolecular hydrogen bond in water
Main axis of a diatomic molecule is z, molecular orbital and overlap to form, which of the following orbital
no bond will
The correct order of dipole moment is
The common features among the species , and are
bond order three and iso electronic
bond order three and weak field ligands
bond order two and -acceptors
iso electronic and weak field ligands
Molecular structure of , and are
different with 1.0 and 2 lane pairs of electrons respectively
the same, with 1,1 and 1 lone pairs of electrons respectively
different, with 0, 1 and 2 lone pairs of electrons respectively
the same, with 2, 0 and I lone pairs of electrons respectively
How many mole of electrons are involved in the reduction of one mole of ion in alkaline medium to
The two sulphur atoms in have
+4 and +6 oxidation state
-2 and +6 oxidation state
same oxidation state
+2 and + 4 oxidation state
The oxidation state of oxygen in Pt
A 2.5 mole of hydrazine loses 25 mole of electrons in being converted to a new compound X. Assuming that all of these nitrogen appear in the new compound, what is the oxidation state of nitrogen in compounds X.
–2
-1
+3
+ 4
In the presence of ions, which of the following species can act as very strong oxidising agent
All
Which of the following statements is /are correct A – Oxyanions are stronger oxidizing agents in acidic than in neutral or basic solution B – Oxyanions can be reduced to a variety of species depending upon the experimental conditions C – ions is stable in basic solution D – None is correct
CB
BCD
DAB
How many moles of nitrogen is produced by the oxidation of one mole of hydrazine by mole bromate ion
Which of the following acids are likely to form Z witterions A –
B – C –
D –
C
BD
D
The set with correct order of acidity is
The conjugate base of is
Which is the decreasing order strength of the bases , and
Which one of the following is the correct order of basic strength.
Which of the following has been arranged correctly in increasing order of acid strength. A – B – C – D –
AD
Which of the following has been arranged in increasing order of acidic strength
Which of the following salts are acidic in aqueous solutions A – B – C – D –
ACD
Among the following which is the strongest protonic acid
Which of the following is the correct order of basic nature of the compounds
IV > III > I > III
I > II > III> VI
III > I > IV > II
Which of the following is the correct order of basic nature of the compounds.
I > III > II > IV
IV > I > III > II
II > IV > I > III
Arrange m-methoxy phenol (A). o- methoxy phenol (B), p- methoxy phenol© and phenol (D) in order or decreasing acid strength
A > D > B > C
A > B >C > D
D > A >C > B
A > D > C> D
The decreasing order of basic character of the amines and ammonia is
Weaker Lewis base
Stronger Lewis base
Weaker Lewis acid
Stronger Lewis acid
I. II, III are three isotherms respectively at and . Temperature will be in order
The vander Waals’ equation is for n moles where a and b are vander Waal’s constant which of the following statements are true about a and b when the temperature of the gas is too low
a varies , b remains same
both remains same
a remains same , b varies
both varies
The circulation of blood in human body supplies and releases . The concentration of and is variable but on the average, 100 ml blood contains 0.02 g of and 0.08 g of . Calculate the volume of and at 1 atm and body temperature , assuming 10 litre blood in human body
2 litre , 4 litre
1.5 litre , 4.5 litre
1.59 litre , 4.62 litre
3.82 litre , 4.62 litre
The tube in the fig. is Shielded at both end and is heated up to double the original temperature both side of Hg column gases are packed with increasing temperature the Hg column
Start to vibrate
Shift towards ‘A’
Shift towards ‘B’
Remains same
When an ideal gas undergoes unrestricted expansion, on cooling takes place because the molecules
Are above the inversion temperatures
Exert no attractive forces
Collide without loss of energy
Do work equal to loss of KE
A closed vessel is maintained at a constant temperature it is first evacuated , and then an ideal gas is introduced into it continuously. The pressure of the gas inside the vessel will
make it burst after some time
first increases and then remains constant
first increases and then decrease
remains constant
For two gases, A and B with molecular weights and , it is observed that at a certain temperature T, the mean velocity of A is equal to the root mean square velocity of B. thus the mean velocity of A can be made equal to the mean velocity of B if
Both A and B are placed at lower temperature
A is at temperature T, and B at T’ and T’ .T > T
Both A and B are raised to a higher temperature
A is lowered to a temperature . While B is at T
The accompanying figure depicts the change in concentration of species A and B for the reaction , as a function of time the point of intersection of the two curves represents
Zero
3/2
Which of the following is correct graph for the reaction
Following is the graph between log and log a (a = initial concentration) for given reaction at . Hence order is
A substance undergoes a first order decomposition. The decomposition follows two parallel first order reactions as The percentage distribution of B and C are
80% B, 20% C
92% B, 8% C
68% B, 32 % C
76.83% B, 23 23.17%
Two substance and . are taken in such away that initially . The time after which both the concentration will be equal is
Concentration can never be equal
5min
15 min
20 min
When chemical equilibrium is attained
In a flask coloured is in equilibrium with brown coloured . At equilibrium when the flask is heated at , the brown colour deepens and on cooling it becomes less coloured, the change in enthalpy, for the system is
Undefined
Positive
Negative
The solubility of would be highest, among the following solvents in
neutral buffer of pH = 7
acidic buffer of pH = 3
basic buffer of pH = 10
pure water
Which of the following acts as the best buffer
Two buffer solution A and B each made with acetic acid and sodium acetate differ in their value of one unit . A has “salt acid = x: y†B has “ salt acid = x : y†x> y, then the value of x: y is
2.10
3.17
10.00
6.16
6
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